which can be used to modify the electronic communication between the Ir centers as well as the various photophysical and physical properties of the complex. In this thesis a range of new diiridium complexes bridged by hydrazide (N^O) chelates will be discussed. In Chapter 2 further structural variation of the peripheral cyclometallating and bridging ligands of the prototypical complex 34 is explored through complexes 35 38.
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